Synthesis and Electrochemical Performance of Electrostatic Self-Assembled Nano-Silicon@N-Doped Reduced Graphene Oxide/Carbon Nanofibers Composite as Anode Material for Lithium-Ion Batteries

نویسندگان

چکیده

Silicon-carbon nanocomposite materials are widely adopted in the anode of lithium-ion batteries (LIB). However, lithium ion (Li+) transportation is hampered due to significant accumulation silicon nanoparticles (Si) and change their volume, which leads decreased battery performance. In an attempt optimize electrode structure, we report on a self-assembly synthesis nanoparticles@nitrogen-doped reduced graphene oxide/carbon nanofiber (Si@N-doped rGO/CNF) composites as potential high-performance anodes for LIB through electrostatic attraction. A large number vacancies or defects graphite plane generated by N atoms, thus providing transmission channels Li+ improving conductivity electrode. CNF can maintain stability structure prevent Si from falling off The three-dimensional composite Si, N-doped rGO, effectively buffer volume changes form stable solid electrolyte interface (SEI), shorten distance electrons, while also high mechanical Si@N-doped rGO/CNF outperforms rGO Si/rGO/CNF electrodes cycle performance rate capability, with reversible specific capacity reaching 1276.8 mAh/g after 100 cycles Coulomb efficiency 99%.

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ژورنال

عنوان ژورنال: Molecules

سال: 2021

ISSN: ['1420-3049']

DOI: https://doi.org/10.3390/molecules26164831